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Optical Material

Zinc Selenide (ZnSe)

Zinc Selenide (ZnSe) is a polycrystalline infrared material with excellent transmission from the visible through the far infrared. It is the standard material for CO₂ laser optics and is widely used in thermal imaging and IR spectroscopy systems.

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Key Optical Properties

Property Value
Transmission Range 0.6 μm – 18 μm
Refractive Index 2.4028 @ 10.6μm
Thermal Expansion 7.1 × 10⁻⁶ /K (20-300°C)
Density 5.27 g/cm³
Knoop Hardness 120 HK
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Advantages

  • Excellent IR transmission (0.6μm to 18μm)
  • Good thermal conductivity for CO₂ lasers
  • Standard material for 10.6μm CO₂ optics
  • Visible and IR transmission — useful for alignment
  • Low absorption at CO₂ wavelength
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Limitations

  • Soft material — easily scratched
  • Toxic material — special handling required
  • High refractive index requires AR coating
  • More expensive than Ge or Si
  • Yellow/orange color (visible light absorption)

Typical Applications

CO₂ laser windows and lenses

Thermal imaging systems

FTIR spectroscopy

Medical laser systems

IR optical sensors

Thermal Properties

Property Value
Coefficient of Thermal Expansion (CTE) 7.1 × 10⁻⁶ /K
Thermal Conductivity 18 W/m·K
dn/dT (Thermo-optic Coefficient) 61 × 10⁻⁶ /K at 10.6 μm
Maximum Operating Temperature ~150°C

ZnSe has moderate thermal properties. The relatively high dn/dT requires thermal consideration in high-power CO₂ laser applications.

Common Coating Options

Standard coating types available for this material. Custom coating designs available on request.

● AR coatings for 10.6μm
● Broadband IR AR (8-12μm)
● Dual-band AR (visible + CO₂)
● Diamond-Like Carbon (DLC)
● Partial reflection for output couplers

Manufacturing Considerations

Machinability

Soft material, easy to machine and diamond turn. One of the easiest IR materials to fabricate.

Polishing

Good polishability with standard methods. Achieves excellent surface finish for CO₂ laser optics.

Environmental Sensitivity

Slight moisture absorption over time. Handle with clean gloves to avoid surface contamination.

Cost & Availability

High cost due to expensive raw material. Premium pricing for large-aperture and high-purity grades.

When to Consider Another Material

No single optical material is perfect for every application. Here are situations where Zinc Selenide (ZnSe) may not be the best fit, and what to consider instead.

When you need High-temperature IR applications (>150°C)

→ Consider: Zinc Sulfide (ZnS)

ZnSe begins to absorb more strongly at elevated temperatures. For sustained high-temperature IR operation, ZnS is more thermally stable.

When you need Mechanical durability in field conditions

→ Consider: Zinc Sulfide or hard-coated alternatives

ZnSe is soft (Mohs ~2.5) and prone to scratching. For field-deployed optics exposed to dust, sand, or cleaning, ZnS or hard-coated ZnSe offer better survival.

When you need SWIR-only applications (1-3μm)

→ Consider: Silicon or Sapphire

ZnSe's advantage is broadband IR transmission, but if you only need SWIR, silicon is significantly cheaper with better mechanical properties.

When you need Lightweight optical systems

→ Consider: Silicon

ZnSe has a density of 5.27 g/cm³. For weight-critical applications, silicon at 2.33 g/cm³ is less than half the weight.

Products Using ZnSe (Zinc Selenide)

Browse our catalog of precision optical components available in Zinc Selenide (ZnSe)

Windows

ZnSe Circular/Square Windows

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Filters

IR Transmission Visible Absorption Filters

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Polarizers

IR Polarizers

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When to Consider Another Material

Consider ZnS if mechanical durability is a higher priority. ZnSe offers excellent broadband IR transmission but is softer and more susceptible to damage. Avoid in high-power laser applications without proper coating.

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