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Optical Material

Sapphire (Al₂O₃)

Sapphire is a single-crystal form of aluminum oxide (Al₂O₃) with extraordinary mechanical, thermal and optical properties. Its extreme hardness and broad transmission make it the material of choice for demanding environments where durability matters.

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Key Optical Properties

Property Value
Transmission Range 170 nm – 5.5 μm
Refractive Index 1.768 @ 587.6nm (ordinary)
Thermal Expansion 5.3 × 10⁻⁶ /K (20-300°C)
Density 3.97 g/cm³
Knoop Hardness 2200 HK
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Advantages

  • Extremely hard and scratch-resistant (2nd only to diamond)
  • Very broad transmission (UV to mid-IR)
  • Excellent thermal conductivity
  • High melting point (2040°C)
  • Chemically inert and biocompatible
  • Excellent abrasion and wear resistance
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Limitations

  • Birefringent material (not isotropic)
  • Higher cost than glass materials
  • Difficult to process and polish
  • High refractive index requires good AR coating
  • Material size limitations for large optics

Typical Applications

Extreme-environment windows

Medical and dental optics

Aerospace and defense systems

High-pressure and vacuum systems

Wear-resistant optical surfaces

Thermal Properties

Property Value
Coefficient of Thermal Expansion (CTE) 5.0 × 10⁻⁶ /K (⊥), 5.3 × 10⁻⁶ /K (∥)
Thermal Conductivity 35 W/m·K
dn/dT (Thermo-optic Coefficient) 13.8 × 10⁻⁶ /K
Maximum Operating Temperature ~1800°C (melting point 2050°C)

Sapphire exhibits excellent thermal shock resistance due to high thermal conductivity and moderate CTE. Suitable for extreme temperature environments.

Common Coating Options

Standard coating types available for this material. Custom coating designs available on request.

● Broadband AR (UV-VIS-NIR)
● Mid-wave IR AR coatings
● Diamond-Like Carbon (DLC)
● Anti-reflection for multi-band use
● High-temperature resistant coatings

Manufacturing Considerations

Machinability

Very hard (9 Mohs), requires diamond tooling throughout. Slow machining rate increases fabrication time.

Polishing

Excellent polish achievable but time-consuming process. Requires specialized polishing methods for hard materials.

Environmental Sensitivity

Excellent chemical and scratch resistance. Virtually inert in most environments. Ideal for harsh conditions.

Cost & Availability

High cost, especially for large apertures. Crystal growth limitations affect maximum available size.

When to Consider Another Material

No single optical material is perfect for every application. Here are situations where Sapphire may not be the best fit, and what to consider instead.

When you need Isotropic optical performance required

→ Consider: Fused Silica or BK7

Sapphire is birefringent (ordinary and extraordinary rays differ). In polarization-sensitive systems, this can cause problems. Isotropic materials like fused silica or BK7 avoid this issue.

When you need Broad UV transmission below 150nm

→ Consider: UV Fused Silica or CaF₂

Sapphire transmits down to about 150nm, but fused silica reaches deeper UV (~180nm) more cost-effectively. For vacuum UV, CaF₂ extends further.

When you need Cost-sensitive projects

→ Consider: BK7 or Borosilicate

Sapphire is expensive due to its crystal growth process and machining difficulty. For applications that don't require extreme hardness, BK7 is a budget-friendly alternative.

When you need Complex aspherical optics

→ Consider: BK7 or Fused Silica

Sapphire's extreme hardness (Mohs 9) makes grinding and polishing difficult and costly. For complex geometries, BK7 or fused silica are easier to fabricate.

Products Using Sapphire

Browse our catalog of precision optical components available in Sapphire

Windows

Sapphire Circular/Square Windows

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View All Sapphire Products

When to Consider Another Material

Consider fused silica or BK7 if extreme hardness is not required — sapphire is more expensive and difficult to polish. Sapphire is the right choice when scratch resistance, chemical inertness or high-temperature stability are critical.

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